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91.
Composite granite–quartz veins occur in retrogressed ultrahigh pressure (UHP) eclogite enclosed in gneiss at General's Hill in the central Sulu belt, eastern China. The granite in the veins has a high‐pressure (HP) mineral assemblage of dominantly quartz+phengite+allanite/epidote+garnet that yields pressures of 2.5–2.1 GPa (Si‐in‐phengite barometry) and temperatures of 850–780°C (Ti‐in‐zircon thermometry) at 2.5 GPa (~20°C lower at 2.1 GPa). Zircon overgrowths on inherited cores and new grains of zircon from both components of the composite veins crystallized at c. 221 Ma. This age overlaps the timing of HP retrograde recrystallization dated at 225–215 Ma from multiple localities in the Sulu belt, consistent with the HP conditions retrieved from the granite. The εHf(t) values of new zircon from both components of the composite veins and the Sr–Nd isotope compositions of the granite consistently lie between values for gneiss and eclogite, whereas δ18O values of new zircon are similar in the veins and the crustal rocks. These data are consistent with zircon growth from a blended fluid generated internally within the gneiss and the eclogite, without any ingress of fluid from an external source. However, at the peak metamorphic pressure, which could have reached 7 GPa, the rocks were likely fluid absent. During initial exhumation under UHP conditions, exsolution of H2O from nominally anhydrous minerals generated a grain boundary supercritical fluid in both gneiss and eclogite. As exhumation progressed, the volume of fluid increased allowing it to migrate by diffusing porous flow from grain boundaries into channels and drain from the dominant gneiss through the subordinate eclogite. This produced a blended fluid intermediate in its isotope composition between the two end‐members, as recorded by the composite veins. During exhumation from UHP (coesite) eclogite to HP (quartz) eclogite facies conditions, the supercritical fluid evolved by dissolution of the silicate mineral matrix, becoming increasingly solute‐rich, more ‘granitic’ and more viscous until it became trapped. As crystallization began by diffusive loss of H2O to the host eclogite concomitant with ongoing exhumation of the crust, the trapped supercritical fluid intersected the solvus for the granite–H2O system, allowing phase separation and formation of the composite granite–quartz veins. Subsequently, during the transition from HP eclogite to amphibolite facies conditions, minor phengite breakdown melting is recorded in both the granite and the gneiss by K‐feldspar+plagioclase+biotite aggregates located around phengite and by K‐feldspar veinlets along grain boundaries. Phase equilibria modelling of the granite indicates that this late‐stage melting records P–T conditions towards the end of the exhumation, with the subsolidus assemblage yielding 0.7–1.1 GPa at <670°C. Thus, the composite granite–quartz veins represent a rare example of a natural system recording how the fluid phase evolved during exhumation of continental crust. The successive availability of different fluid phases attending retrograde metamorphism from UHP eclogite to amphibolite facies conditions will affect the transport of trace elements through the continental crust and the role of these fluids as metasomatic agents interacting with the mantle wedge in the subduction channel.  相似文献   
92.
The North American Land Data Assimilation System project phase 2 (NLDAS‐2) has run four land surface models for a 30‐year (1979–2008) retrospective period. Land surface evapotranspiration (ET) is one of the most important model outputs from NLDAS‐2 for investigating land–atmosphere interaction or to monitor agricultural drought. Here, we evaluate hourly ET using in situ observations over the Southern Great Plains (Atmospheric Radiation Measurement/Cloud and Radiation Testbed network) for 1 January 1997–30 September 1999 and daily ET u‐sing in situ observations at the AmeriFlux network over the conterminous USA for an 8‐year period (2000–2007). The NLDAS‐2 models compare well against observations, with the National Centers for Environmental Prediction's Noah land surface model performing best, followed, in order, by the Variable Infiltration Capacity, Sacramento Soil Moisture Accounting, and Mosaic models. Daily evaluation across the AmeriFlux network shows that for all models, performance depends on season and vegetation type; they do better in spring and fall than in winter or summer and better for deciduous broadleaf forest and grasslands than for croplands or evergreen needleleaf forest. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
93.
Understanding hydrological processes in wetlands may be complicated by management practices and complex groundwater/surface water interactions. This is especially true for wetlands underlain by permeable geology, such as chalk. In this study, the physically based, distributed model MIKE SHE is used to simulate hydrological processes at the Centre for Ecology and Hydrology River Lambourn Observatory, Boxford, Berkshire, UK. This comprises a 10‐ha lowland, chalk valley bottom, riparian wetland designated for its conservation value and scientific interest. Channel management and a compound geology exert important, but to date not completely understood, influences upon hydrological conditions. Model calibration and validation were based upon comparisons of observed and simulated groundwater heads and channel stages over an equally split 20‐month period. Model results are generally consistent with field observations and include short‐term responses to events as well as longer‐term seasonal trends. An intrinsic difficulty in representing compressible, anisotropic soils limited otherwise excellent performance in some areas. Hydrological processes in the wetland are dominated by the interaction between groundwater and surface water. Channel stage provides head boundaries for broad water levels across the wetland, whilst areas of groundwater upwelling control discrete head elevations. A relic surface drainage network confines flooding extents and routes seepage to the main channels. In‐channel macrophyte growth and its management have an acute effect on water levels and the proportional contribution of groundwater and surface water. The implications of model results for management of conservation species and their associated habitats are discussed. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
94.
Recent studies using water‐stable isotopes (δ18O and δ2H) have suggested an ecohydrological separation of water flowing to streams or recharging groundwater and water used by trees, known as the ‘two water worlds’ (TWW) hypothesis. In this study, we measured water isotopic composition in precipitation [open field and throughfall, i.e. local meteoric water line (LMWL)] and the mobile water compartment (i.e. stream and soil solution), bulk soil water and xylem water over a period of 1.5 years in two headwater catchments: NF, covered with old growth native evergreen forest (Aetoxicon punctatum, Laureliopsis philippiana and Eucriphya cordifolia), and EP, covered with 4 and 16‐year‐old Eucalyptus nitens stands. Our results show that precipitation, stream and soil solution plot approximately along the LMWL, while xylem waters from all studied tree species plot below the LMWL, supporting the TWW hypothesis. However, we also found evidence of ecohydrological connectivity during the wet season, likely controlled by the amount of antecedent precipitation. These observations hold for all investigated tree species. On both sites, a different precipitation source for stream and xylem water was observed. However, in EP, bulk soil showed a similar precipitation source as xylem water from both E. nitens stands. This suggests that E. nitens may use water that is recharging the bulk soil compartment. We conclude that under a rainy temperate climate, the TWW hypothesis is temporal and does not apply during wet seasons. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
95.
96.
Behavior of unsaturated soils is influenced by many factors, and the influences of these factors are usually coupled together. Suction‐controlled triaxial (SCTX) tests are considered to allow researchers to investigate influences of individual variables on unsaturated soils under specified stress path with controls of stresses, pore water, and air pressures. In the past 50 years, SCTX testing method has been established as a standard approach to characterize constitutive behavior of unsaturated soils. Most important concepts for modern unsaturated soil mechanics were developed upon results from the SCTX tests. Among these, one of the most important contributions in the constitutive modeling of elasto‐plastic behavior for unsaturated soils is the Barcelona basic model (BBM) proposed by Alonso et al. in 1990. The BBM successfully explained many features of unsaturated soils and received extensive acceptance. However, the SCTX tests are designed based upon the divide‐and‐conquer approach in which an implicit assumption is used: soil behavior is stress‐path independent. However, it is well‐established that unsaturated soil behavior is elasto‐plastic and stress‐path dependent. It is found that the SCTX tests in fact cannot control the stress path of an unsaturated soil during loading. This incapability, in combination with complicated loading/collapse behavior of unsaturated soils, makes the SCTX tests for characterizing unsaturated soil questionable. This paper discusses the limitations of the SCTX tests in the characterization of unsaturated soils. A possible solution to the problem was proposed based on a newly developed modified state surface approach. The discussions are limited for isotropic conditions. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
97.
An effective approach to modeling the geomechanical behavior of the network and its permeability variation is to use a poroelastic displacement discontinuity method (DDM). However, the approach becomes rather computationally intensive for an extensive system of cracks, particularly when considering coupled diffusion/deformation processes. This is because of additional unknowns and the need for time‐marching schemes for the numerical integration. The Fast Multipole Method (FMM) is a technique that can accelerate the solution of large fracture problems with linear complexity with the number of unknowns both in memory and CPU time. Previous works combining DDM and FMM for large‐scale problems have accounted only for elastic rocks, neglecting the fluid leak‐off from the fractures into the matrix and its influence on pore pressure and stress field. In this work we develop an efficient geomechanical model for large‐scale natural fracture networks in poroelastic reservoirs with fracture flow in response to injection and production operations. Accuracy and computational performance of the proposed method with those of conventional poroelastic DDM are compared through several case studies involving up to several tens of thousands of boundary elements. The results show the effectiveness of the FMM approach to successfully evaluate field‐scale problems for the design of exploitation strategies in unconventional geothermal and petroleum reservoirs. An example considering faults reveals the impact of reservoir compartmentalization because of sealing faults for both geomechanical and flow variables under elastic and poroelastic rocks. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
98.
利用CitesSpace软件对1997-2017年DMSP/OLS夜间灯光数据进行知识图谱分析,梳理国内外研究热点与演化历史,发掘研究难点,为后来研究者提供方向。本文选取Web of Science 核心数据集数据库收录的文献,进行合著特征分析、关键词共现分析和文献共被引分析。结果表明:① 夜间灯光数据相关研究最活跃的国家、机构和作者分别是美国、中国科学院和Elvidge;② 社会经济条件估计(人口、人口密度和电力)和城市扩展变化监测一直是国内外研究的热点和前沿;③ 目前的研究难点是如何减少灯光溢出效应以及灯光过饱和现象对研究精度的影响;④ 研究学科交叉性强,涉及地理学、测绘科学与技术、应用经济学、社会学等领域。因此,未来的研究趋势主要表现在数据处理方法的优化、研究领域的拓展以及深化已有研究成果3个方面。  相似文献   
99.
Ambient air polycyclic aromatic hydrocarbon (PAH) samples were collected at a suburban (n = 63) and at an urban site (n = 14) in Izmir, Turkey. Average gas‐phase total PAH (∑14PAH) concentrations were 23.5 ng m?3 for suburban and 109.7 ng m?3 for urban sites while average particle‐phase total PAH concentrations were 12.3 and 34.5 ng m?3 for suburban and urban sites, respectively. Higher ambient PAH concentrations were measured in the gas‐phase and ∑14PAH concentrations were dominated by lower molecular weight PAHs. Multiple linear regression analysis indicated that the meteorological parameters were effective on ambient PAH concentrations. Emission sources of particle‐phase PAHs were investigated using a diagnostic plot of fluorene (FLN)/(fluorine + pyrene; PY) versus indeno[1,2,3‐cd]PY/(indeno[1,2,3‐cd]PY + benzo[g,h,i]perylene) and several diagnostic ratios. These approaches have indicated that traffic emissions (petroleum combustion) were the dominant PAH sources at both sites for summer and winter seasons. Experimental gas–particle partition coefficients (KP) were compared to the predictions of octanol–air (KOA) and soot–air (KSA) partition coefficient models. The correlations between experimental and modeled KP values were significant (r2 = 0.79 and 0.94 for suburban and urban sites, respectively, p < 0.01). Octanol‐based absorptive partitioning model predicted lower partition coefficients especially for relatively volatile PAHs. However, overall there was a relatively good agreement between the measured KP and soot‐based model predictions.  相似文献   
100.
Ulmus carpinifolia tree leaves were successfully used to remove Tl(I) from aqueous solution in a batch system. In order to improve the uptake capacity of sorbent, it was modified by various chemical agents such as NaOH, HNO3, NH3, NaCl, NaHCO3, and CaCl2. Among the modifiers, NaCl was the best. Equilibrium behavior of sorbent with Tl(I) was examined by the several isotherms. Considering modified U. carpinifolia equilibrium data fitted well to the Langmuir model with maximum capacity of 54.6 mg/g. The other isotherms such as: Freundlich and Dubinin‐Redushkevich (D‐R) models were also examined. The central composite design (CCD) was successfully employed for optimization of biosorption process. An empirical model was given through using response surface methodology. Also its validation was recognized by using relevant statistical tests such as ANOVA. The optimum conditions of biosorption: pH, m (amount of sorbent) and C (initial concentration) were found to be 7.9, 11.4 g/L, and 8.8 mg/L, respectively. On the other hand thermodynamic parameters: ΔG, ΔH, and ΔS were evaluated: the obtained results show that biosorption process was spontaneous and exothermic. Eventually, FT‐IR analysis confirmed that the main functional groups of sorbent have been involved through the biosorption process.  相似文献   
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